Silfluo

Cyclic Silazane Monomers

SILZ-CY-3 — 2,2,4,4,6,6-Hexamethylcyclotrisilazane (HMCTS)

CAS Registry Number: 1009-93-4

SILZ-CY-3 is hexamethylcyclotrisilazane (HMCTS) — a low-molecular-weight liquid cyclic silazane at ≥96% purity. Its Si-N ring opens under controlled polymerization to build high-purity polysilazane precursors with tailored degrees of polymerization, and it serves photovoltaic and semiconductor workflows as a silylation and protective-coating raw material.

Samples
from 1 kg
MOQ
No strict minimum
Lead time
~14 working days
Documents
TDS · SDS · COA
Request a Sample
Silfluo SILZ-CY-3 2,2,4,4,6,6-hexamethylcyclotrisilazane (hmcts)

Product Overview

Ring-opening polymerization is the headline use: starting from the clean, defined trimer, precursor makers set molecular weight and architecture on their own terms — the route to high-purity polysilazanes for electronics-adjacent applications. Blended with reactive organosilazanes such as methylhydrosilazane, HMCTS becomes part of Si-C-N ceramic fiber precursor systems.

Alongside synthesis duty, Si-N bonds react with hydroxyl compounds — amine-type curing-agent behavior — and modify phenolic, epoxy, alkyd and acrylic resins for heat and weather resistance. In silicone rubber processing HMCTS functions as a structure-control additive that improves vulcanizate strength and heat resistance.

Key Benefits

Defined cyclic trimer, CAS-listed

A clean, single-structure liquid monomer (MW 218–221) with a public CAS registry number — straightforward to qualify, import and register.

Ring-opening polymerization feedstock

The controlled route to high-purity polysilazane precursors — set your own molecular weight and end-group chemistry.

Photovoltaic & semiconductor pedigree

Used in weather-resistant, self-cleaning protective applications across PV and semiconductor supply chains.

Easy-handling liquid

11 s viscosity flows directly into synthesis reactors, blends and impregnation baths without dilution.

Typical Applications

  • PV & semiconductor protective coatings
  • Si-C-N ceramic fibers (blended with methylhydrosilazane)
  • Silicone rubber additive
  • Polysilazane synthesis monomer

Solution guides: Ceramic Precursors & Advanced Ceramics

Technical Data

Coating Performance
Test ItemPerformance IndicatorTest Method
AppearanceColorless transparent liquidGB/T 1721-79
Viscosity (Ford Cup 4)11 sGB/T 1723-1993
Purity≥96%Q/YX 10-2023
Solid Content (120 ± 2°C)>98%GB/T 1725-2007
Density0.92 ± 0.01 g/mLGB/T 6750-2007
Molecular Weight218–221GB/T 27843-2011
Pencil Hardness (as film)≥2HGB/T 6739-2006
AdhesionGrade 0GB/T 9286-1998
Salt Spray Resistance>500 hGB/T 1771-2007
Application Parameters
Physical FormLiquid cyclic trimer (HMCTS)
Cure BehaviorLow Si-CH₃ reactivity — blend with reactive organosilazanes to thermally cure
Cure @165–250 °C (blended, DFT 5–25 µm)Surface dry 1 h → 0.1 h · full cure 1 h → 0.5 h

Values from the SILZ-CY-3 technical data sheet. Complete TDS with test conditions available on request.

Curing & Processing Guidance

Handle under dry, inert conditions — the Si-N ring is moisture-reactive, and purity is the product. Keep containers sealed and transfer with dry equipment.

SILZ-CY-3 does not thermally cure on its own: Si-CH₃ groups are low-reactivity by design. For film or ceramic work, blend with reactive organosilazanes (e.g., methylhydrosilazane SILZ-701); blended systems follow the standard 165–250 °C cure window with surface-dry from 1 hour down to 6 minutes.

For ring-opening polymerization, catalyst choice and conditions define your precursor architecture — our lab shares starting conditions for common target molecular weights.

Substrate Compatibility

Primarily a synthesis and compounding raw material — the "substrate" is your reactor or resin system. As part of blended coating systems, standard metallic and ceramic substrates apply after conventional preparation.

SILZ-CY-3 — Purchasing & Application FAQ

What is the difference between SILZ-CY-3 and SILZ-CY-4?

Same chemistry family, different ring size and physical form: CY-3 (HMCTS) is a liquid trimer, easiest to dose and react; CY-4 (OMCTS) is a solid tetramer with a defined boiling point, preferred where its melting/boiling behavior or tetramer ring suits the synthesis. Many precursor routes qualify both and choose by process convenience.

Can SILZ-CY-3 be used directly as a coating?

Not alone — Si-CH₃ groups make it hard to thermally cure by itself. Blend it with reactive organosilazanes (such as methylhydrosilazane) to build curable films or Si-C-N ceramic fiber precursors.

What purity and documentation ship with it?

≥96% purity to Q/YX 10-2023, with TDS, SDS and batch COA. If your semiconductor or PV workflow needs tighter specification windows, talk to us about qualification lots.

TDS / SDS / COA & Samples

Technical Data Sheet, Safety Data Sheet and batch Certificate of Analysis are available for SILZ-CY-3, and a COA accompanies every shipment. Evaluation samples ship with starting-parameter guidance.

Packaging: Available in 1 kg, 2 kg, 5 kg and 25 kg sealed containers. Keep dry and tightly closed at all times.

SDS & batch COA on request · Reply within 1 business day.

Reply within 1 business day