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Reactive Silazanes & Ceramic Precursors

SILZ-350 — Methylhydro-/Methylvinylsilazane (Heat-Curable Ceramic Precursor)

SILZ-350 is a heat-curing silazane carrying both Si-H and Si-vinyl reactive groups on a Si-N backbone. Cured at 180–250 °C, it converts toward SiCNO/SiCN ceramic structures at high temperature, making it a workhorse precursor for Si-C-N ceramics and a dual-function modifier for unsaturated and hydroxyl-functional resin systems.

Cross-reference: comparable evaluation target Durazane® 1800 *For comparative evaluation only; does not imply composition or performance equivalence. Confirm suitability by application testing.

Samples
from 1 kg
MOQ
No strict minimum
Lead time
~14 working days
Documents
TDS · SDS · COA
Request a Sample
Silfluo SILZ-350 methylhydro-/methylvinylsilazane (heat-curable ceramic precursor)

Product Overview

The dual functionality is the point: Si-H sites drive hydrosilylation with unsaturated olefins, while Si-N and Si-H bonds react readily with hydroxyl-containing substances — so one precursor serves ceramic conversion, amine-type curing-agent duty and heat-resistance modification of phenolic, epoxy, alkyd and acrylic resins.

As a coating binder it delivers ≥6H hardness and >500 h salt spray from a thin 10 µm-class film, serving continuously at 350 °C; compounded with heat-resistant nanofillers it withstands direct flame and high-temperature airflow erosion.

Key Benefits

Dual Si-H / Si-vinyl reactivity

Hydrosilylation sites plus vinyl unsaturation in one molecule — a self-contained crosslinking pair for ceramic and hybrid systems.

High-molecular-weight grade

Relative molecular mass >8×10⁴ builds film integrity and ceramic yield that low-MW silazanes cannot match.

Si-C-N ceramic precursor

Thermal conversion to SiCNO/SiCN or silica ceramics — the raw material route to ceramic coatings, fibers and matrix composites.

Thin-film protection at 350 °C

A cured 10 µm-class film gives ≥6H hardness, >500 h salt spray and continuous 350 °C service with 500 °C excursions.

Typical Applications

  • Si-C-N ceramic precursor
  • Flame/high-temperature airflow-resistant coatings with nanofillers
  • Heat/weather-resistance modification of phenolic, epoxy, alkyd and acrylic resins

Solution guides: Ceramic Precursors & Advanced CeramicsResin, Rubber & Composite Modification

Technical Data

Coating Performance
Test ItemPerformance IndicatorTest Method
Color & AppearancePale yellow to colorless transparent liquidGB/T 1721-1979
Viscosity (Ford Cup 4)35–50 sGB/T 1723-1993
Purity≥95%Q/YX 10-2023
Solid Content (120 ± 2°C)>98%GB/T 1725-2007
Density1.05 ± 0.01 g/mLGB/T 6750-2007
Relative Molecular Mass>8×10⁴GB/T 27843-2011
Pencil Hardness≥6HGB/T 6739-2006
AdhesionGrade 0GB/T 9286-1998
Salt Spray Resistance>500 hGB/T 10125-2021
Application Parameters
Reactive GroupsSi-H + Si-vinyl (methylhydro- & methylvinylsilazane)
DilutionHigh viscosity — 50% dilution recommended before application
Theoretical Coverage12–28 m²/kg
Curing Temperature180–250 °C
Curing Time1 h
Dry Film Thickness10 ± 5 µm (keep ≤15 µm)
Working Time (after opening)24 h
Recommended Operating Temperature-30 to 300 °C (continuous 350 °C, max 500 °C)
ThinnerAromatics, esters, ethers
Flash Point<22 °C (solvent)
Storage Temperature0–30 °C

Values from the SILZ-350 technical data sheet. Complete TDS with test conditions available on request.

Curing & Processing Guidance

SILZ-350 is supplied as a high-viscosity varnish (35–50 s, Ford Cup 4); dilute about 50% with aromatic, ester or ether solvents before spraying. Prepare metal substrates to Sa 2.5 (minimum St 3) and ensure a clean, dry surface.

Apply one thin coat targeting 10 ± 5 µm dry film and do not exceed 15 µm — precursor films densify during cure, and over-thick films lose performance. Theoretical coverage runs 12–28 m²/kg diluted.

Cure at 180–250 °C for about 1 hour. Opened material stays workable for 24 hours; clean tools promptly. For ceramic-conversion work, pyrolysis schedules above the cure window are application-specific — our lab supports thermal-profile design.

Substrate Compatibility

Carbon steel, stainless steel, cast iron, aluminum alloy, titanium alloy, high-temperature alloy steel, glass-ceramics, ceramics and cement. As a resin modifier or ceramic precursor, compatibility is defined by your matrix system — send us the resin or fiber system and target service temperature.

SILZ-350 — Purchasing & Application FAQ

What is the difference between SILZ-350 and SILZ-702?

Both are high-molecular-weight heat-curing silazanes with near-identical film data. SILZ-350 carries Si-H plus vinyl groups (methylhydro- and methylvinylsilazane), giving it a built-in hydrosilylation pair; SILZ-702 is Si-H only. Choose 350 when you want self-crosslinking or vinyl reactivity, 702 when a pure Si-H feedstock fits your chemistry.

Can SILZ-350 be used for ceramic matrix composites?

Yes — thermal conversion to SiCNO/SiCN makes it a standard Si-C-N precursor for coatings, fibers and CMC matrix work. Ceramic yield and phase depend on your pyrolysis atmosphere and schedule; we share starting profiles with samples.

Why must the film stay below 15 µm?

Precursor coatings shrink as they densify during heat cure. Above roughly 15 µm the film accumulates stress and performance drops — build thickness with system design (fillers, multiple thin coats validated per application), not one thick pass.

TDS / SDS / COA & Samples

Technical Data Sheet, Safety Data Sheet and batch Certificate of Analysis are available for SILZ-350, and a COA accompanies every shipment. Evaluation samples ship with starting-parameter guidance.

Packaging: Available in 1 kg, 2 kg, 5 kg and 25 kg pails. Store at 0–30 °C in the original sealed container.

SDS & batch COA on request · Reply within 1 business day.

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